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Stretching is very personal. Like a finely tuned instrument you only need to adjust the correct strings for the perfect tune. Take notice of what feels tight and work on those areas, stretching already long soft tissue (muscles, tendons, fascia) will only further worsen a bad posture. Devote stretching to a time in the day when you are totally relaxed. Stretching after a workout will have little impact because your nervous system is too fired up or sympathetic.